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La catodoluminescenza e l'analisi di immagine per lo studio delle malte. Proceedings of the IV Congresso Nazionale di Archeometria Scienza e Beni Culturali. Pise, Febraury 2006. Goren, Y. & Goring-Morris, AN. (2008). Early Pyrotechnology in the Near East: Experimental Lime-Plaster Production at the Pre-Pottery Neolithic B Site of Kfar HaHoresh, Israel. Geoarchaeology: An International Journal, 23, 6, pp. , & Ringbom, A. (2003). Dating ancient mortar. American Scientist, 91, pp. 130-137 Ingham, JP.
337–343. , Pachiaudi, C. & Marechal, J. (1986). The influence of contaminating (fossil) carbonate and the variations of delta-C-13 in mortar dating, Radiocarbon, Vol. 28, No. 2A, pp. 702-710, ISSN 0033-8222 Van Strydonck, M. , (1991). A. C. ), pp. 5-43, Tempus Reparatum ISBN 0860547272, Oxford Van Strydonck, M. J. , De Jong, A. F. M. & Keppens, E. (1992). Radiocarbon dating of lime fractions and organic material from buildings, Radiocarbon, Vol. 34, pp. 873–879, ISSN 0033-8222 Warkentin, B. P. , (1980).
2. , 2007). From a chemical point of view, carbonation is the reaction between calcium ions (Ca2+) and carbonate ions (CO32-) in aqueous solution. This leads to the precipitation of a solid calcium carbonate phase, as described by the following reaction scheme: - - dissolution of carbon dioxide (CO2) in water (Morse & Mackenzie, 1990): CO2(g) ↔ CO2(aq) (1) CO2(aq) + H2O(l) ↔ H2CO3(aq) (2) H2CO3(aq) ↔ HCO3-(aq) + H+(aq) (3) HCO3-(aq) ↔ CO32-(aq) + H+(aq) (4) dissolution of calcium hydroxide (Ca(OH)2) in water: Ca(OH)2(s) + H2O(l) ↔ Ca2+(aq) + 2(OH-)(aq)+ H2O(l) - (5) reaction of calcium ions with carbonate ions in water solution: Ca2+(aq) + CO32-(aq) + H2O(l) ↔ CaCO3(s) + H2O(l) (6) Dating of Old Lime Based Mixtures with the “Pure Lime Lumps” Technique 23 These reactions describe the dissolution of atmospheric carbon dioxide (CO2) in water (reaction 1) and the subsequent reaction forming carbonic acid (2).