By John S Shearer
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Therefore, it is necessary to use the values published for the surface energy for all applications. From the considerations above it is clear that the determination of the surface energy by measuring the interface stress is not sufficient. g. connected to grain growth, result in a value for the surface energy. Lastly, only these values are useful for thermodynamic considerations. In the case of anisotropic lattices, the relations are more complex since there are directional bonds. The surface energy of these materials depends on the direction; hence, to minimize surface energy, these materials crystallize in rods or platelets.
Int. , 40, 4128–4158. 1 General Considerations The surface forms a sharp interface between a particle and the surrounding atmosphere or between a precipitated phase and the parent phase. In mathematics, the surface of a body, for example, a sphere or a polyhedron, is clearly defined. As already mentioned in Chapter 2, in a sphere, the ratio surface over volume is indirectly proportional to the diameter. This is different in the case of a real, physically existing material. In this case, one has to distinguish between free surfaces in the case of particulate materials and grain boundaries in bulk material.
2 Vollath, D. (2010) Adv. , 22, 4410–4415. V. (1999) J. , 1, 235–242. M. (2001) Angew. Chem. Int. , 40, 4128–4158. 1 General Considerations The surface forms a sharp interface between a particle and the surrounding atmosphere or between a precipitated phase and the parent phase. In mathematics, the surface of a body, for example, a sphere or a polyhedron, is clearly defined. As already mentioned in Chapter 2, in a sphere, the ratio surface over volume is indirectly proportional to the diameter.